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C1 Chemistry on Metal Carbide Nanoparticles: Boosting the Conversion of CO2 and CH4

dc.contributor.authorRodriguez J.A
dc.contributor.authorJimenez-Orozco C
dc.contributor.authorFlórez E
dc.contributor.authorViñes F
dc.contributor.authorIllas F.
dc.date.accessioned2024-07-31T21:07:12Z
dc.date.available2024-07-31T21:07:12Z
dc.date.created2023
dc.identifier.issn19327447
dc.identifier.urihttp://hdl.handle.net/11407/8501
dc.descriptionThe studies described in this Perspective show that transition metal carbide (TMC) nanoparticles can be very useful for the activation of three molecules located at the heart of C1 chemistry: H2, CH4, and CO2. They also can play a major role in the trapping and conversion of two major greenhouse gases. A combination of experiment and theory has shed light on the physical and chemical properties of these systems, which can be very different from those of bulk carbides. Molecular clusters of these compounds, which can be inserted inside the cages of zeolites or carbon nanotubes, have unsaturated metal and carbon atoms that frequently work in a cooperative way when dealing with hard-to-activate molecules, such as CH4 and CO2. These molecular clusters can evolve into nanoparticles of small to medium size (<15 nm) that have unique carbon/metal ratios and structures not seen in the bulk metal carbides. Even when their structures are cuts from bulk lattices, the TMC nanoparticles have corner or edge atoms that are active for the cleavage and conversion of C-H and C-O bonds. Here, we cover experimental and theoretical studies with well-defined metal carbide nanoparticles prepared by different methods, free and supported on diverse substrates. The Perspective ends with a discussion of current challenges and potential applications. © 2023 American Chemical Society.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85170280344&doi=10.1021%2facs.jpcc.3c04541&partnerID=40&md5=2baaa11382e0caba13e082e77091bc19
dc.sourceJournal of Physical Chemistry C
dc.sourceJ. Phys. Chem. C
dc.sourceScopus
dc.subjectCarbideseng
dc.subjectGreenhouse gaseseng
dc.subjectMetal nanoparticleseng
dc.subjectMoleculeseng
dc.subjectTransition metalseng
dc.subjectUnsaturated compoundseng
dc.subjectZeoliteseng
dc.subjectCarbide nanoparticleseng
dc.subjectCarbon atomseng
dc.subjectCH 4eng
dc.subjectGreenhouses gaseng
dc.subjectMetal atomseng
dc.subjectMetal-carbideeng
dc.subjectMolecular clusterseng
dc.subjectPhysical and chemical propertieseng
dc.subjectTransition metals carbideseng
dc.subjectUnsaturated metalseng
dc.subjectCarbon dioxideeng
dc.titleC1 Chemistry on Metal Carbide Nanoparticles: Boosting the Conversion of CO2 and CH4eng
dc.typearticle
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.type.spaArtículo
dc.identifier.doi10.1021/acs.jpcc.3c04541
dc.publisher.facultyFacultad de Ciencias Básicasspa
dc.affiliationRodriguez, J.A., Chemistry Division, Brookhaven National Laboratory, Upton, NY 11973, United States
dc.affiliationJimenez-Orozco, C., Facultad de Ciencias Básicas, Grupo de Materiales con Impacto (Mat&mpac), Universidad de Medellín, Carrera 87 No 30-65 Medellın050021, Colombia
dc.affiliationFlórez, E., Facultad de Ciencias Básicas, Grupo de Materiales con Impacto (Mat&mpac), Universidad de Medellín, Carrera 87 No 30-65 Medellın050021, Colombia
dc.affiliationViñes, F., Departament de Ciència dels Materials i Química Fisica & Institut de Química Teòrica i Computacional (IQTCUB), Universitat de Barcelona, Martí i Franqués 1-11, Barcelona, 08028, Spain
dc.affiliationIllas, F., Departament de Ciència dels Materials i Química Fisica & Institut de Química Teòrica i Computacional (IQTCUB), Universitat de Barcelona, Martí i Franqués 1-11, Barcelona, 08028, Spain
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dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellín
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.instnameinstname:Universidad de Medellín


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