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Highly Adsorptive Organic Xerogels for Efficient Removal of Metformin from Aqueous Solutions: Experimental and Theoretical Approach

dc.contributor.authorAguilar-Maruri S.A.
dc.contributor.authorPerera-Triana D.
dc.contributor.authorFlórez E.
dc.contributor.authorForgionny A.
dc.contributor.authorPalestino G.
dc.contributor.authorGómez-Durán C.F.A.
dc.contributor.authorOcampo-Pérez R.
dc.date.accessioned2024-12-27T20:51:43Z
dc.date.available2024-12-27T20:51:43Z
dc.date.created2024
dc.identifier.issn22279717
dc.identifier.urihttp://hdl.handle.net/11407/8682
dc.descriptionMetformin, widely prescribed to treat type 2 diabetes for its effectiveness and low cost, has raised concerns about its presence in aqueous effluents and its potential environmental and public health impacts. To address this issue, xerogels were synthesized from resorcinol and formaldehyde, with molar ratios ranging from 0.05 to 0.40. These xerogels were thoroughly characterized using FT-IR, SEM, TGA, and TEM analyses. Batch adsorption experiments were performed with standard metformin solutions at concentrations of 50 and 500 mg/L, varying pH, and temperature to determine the adsorption isotherms of the synthesized xerogels. The adsorption data revealed a maximum adsorption capacity of 325 mg/g at pH 11 and 25 °C. Quantum chemical calculations revealed that electrostatic interactions govern metformin adsorption onto xerogels. The xerogels’ adsorption capacity was evaluated in competitive systems with CaCl2, NaCl, MgCl2, and synthetic urines. Reuse cycles demonstrated that xerogels could be reused for up to three cycles without any loss in adsorptive efficiency. The adsorption mechanisms of metformin in the adsorption process highlight the strong electrostatic interactions and hydrogen bonds between the adsorbate and the adsorbent material. Xerogels synthesized show promise as efficient adsorbents to remove metformin from aqueous solutions, helping to mitigate its environmental impact. © 2024 by the authors.
dc.language.isoeng
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85199643501&doi=10.3390%2fpr12071431&partnerID=40&md5=768193e62619512768aec6a41bb33135
dc.sourceProcesses
dc.sourceProcess.
dc.sourceScopus
dc.subjectAdsorptioneng
dc.subjectMetformineng
dc.subjectXerogelseng
dc.subjectAdsorption isothermseng
dc.subjectEffluentseng
dc.subjectElectrostaticseng
dc.subjectHydrogen bondseng
dc.subjectMagnesium compoundseng
dc.subjectMolar ratioeng
dc.subjectQuantum chemistryeng
dc.subjectSodium chlorideeng
dc.subjectAdsorption capacitieseng
dc.subjectAqueous effluenteng
dc.subjectExperimental approacheseng
dc.subjectHealth impacteng
dc.subjectLow-costseng
dc.subjectMetforminseng
dc.subjectOrganicseng
dc.subjectSynthesisedeng
dc.subjectTheoretical approacheng
dc.subjectType-2 diabeteseng
dc.subjectAdsorptioneng
dc.titleHighly Adsorptive Organic Xerogels for Efficient Removal of Metformin from Aqueous Solutions: Experimental and Theoretical Approacheng
dc.typeArticle
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.type.spaArtículo de revista
dc.identifier.doi10.3390/pr12071431
dc.relation.citationvolume12
dc.relation.citationissue7
dc.publisher.facultyFacultad de Ciencias Básicas
dc.affiliationAguilar-Maruri S.A., Centro de Investigación y Estudios de Posgrado, Facultad de Ciencias Químicas, Universidad Autónoma de San Luis Potosí, San Luis Potosí, 78260, Mexico
dc.affiliationPerera-Triana D., Centro de Investigación y Estudios de Posgrado, Facultad de Ciencias Químicas, Universidad Autónoma de San Luis Potosí, San Luis Potosí, 78260, Mexico
dc.affiliationFlórez E., Grupo de Investigación de Materiales con Impacto (MATMPAC), Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, 050026, Colombia
dc.affiliationForgionny A., Grupo de Investigación de Materiales con Impacto (MATMPAC), Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, 050026, Colombia
dc.affiliationPalestino G., Centro de Investigación y Estudios de Posgrado, Facultad de Ciencias Químicas, Universidad Autónoma de San Luis Potosí, San Luis Potosí, 78260, Mexico
dc.affiliationGómez-Durán C.F.A., Centro de Investigación y Estudios de Posgrado, Facultad de Ciencias Químicas, Universidad Autónoma de San Luis Potosí, San Luis Potosí, 78260, Mexico
dc.affiliationOcampo-Pérez R., Centro de Investigación y Estudios de Posgrado, Facultad de Ciencias Químicas, Universidad Autónoma de San Luis Potosí, San Luis Potosí, 78260, Mexico
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dc.type.versioninfo:eu-repo/semantics/publishedVersion
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellín
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.instnameinstname:Universidad de Medellín


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