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Adsorption of Cadmium Using Biochars Produced from Agro-Residues

dc.creatorLópez J.E.
dc.creatorBuiles S.
dc.creatorHeredia Salgado M.A.
dc.creatorTarelho L.A.C.
dc.creatorArroyave C.
dc.creatorAristizábal A.
dc.creatorChavez E.
dc.date2020
dc.date.accessioned2021-02-05T14:57:52Z
dc.date.available2021-02-05T14:57:52Z
dc.identifier.issn19327447
dc.identifier.urihttp://hdl.handle.net/11407/5914
dc.descriptionBiochars have been shown as promising materials for cadmium remediation. However, the different precursors and the pyrolysis process operating conditions can yield very different surface functional groups, and as a result, different cadmium sorption mechanisms can be observed in biochars. Herein we present the results of cadmium sorption on biochars produced from the pyrolysis of different agro-residues, namely, coffee husk, quinoa straw, and oil palm kernel shell. The adsorption isotherms were used to determine the influence of the biochar's physicochemical characteristics to their sorption behavior. The biochars prepared from quinoa residues showed much higher cadmium uptakes than the other biochars. The concentration of base cations was found to be a critical factor for cadmium sorption. Although the quinoa biochars presented large uptakes, it was found that base cations were supported on the biochars and could be removed by leaching. Results from this study suggest that concentration of base cations on biochars could be used as predictors of the biochar capabilities for the removal of cadmium in aqueous solution. Copyright © 2020 American Chemical Society.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85089280277&doi=10.1021%2facs.jpcc.0c02216&partnerID=40&md5=1b13fd14cc8f7905158d219f8eea8c05
dc.sourceJournal of Physical Chemistry C
dc.titleAdsorption of Cadmium Using Biochars Produced from Agro-Residues
dc.typeArticleeng
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.publisher.programIngeniería Ambientalspa
dc.identifier.doi10.1021/acs.jpcc.0c02216
dc.subject.keywordCadmiumeng
dc.subject.keywordPalm oileng
dc.subject.keywordPositive ionseng
dc.subject.keywordPyrolysiseng
dc.subject.keywordSorptioneng
dc.subject.keywordCritical factorseng
dc.subject.keywordDifferent precursorseng
dc.subject.keywordOperating conditioneng
dc.subject.keywordPhysicochemical characteristicseng
dc.subject.keywordPyrolysis processeng
dc.subject.keywordSorption behaviorseng
dc.subject.keywordSorption mechanismeng
dc.subject.keywordSurface functional groupseng
dc.subject.keywordChemicals removal (water treatment)eng
dc.relation.citationvolume124
dc.relation.citationissue27
dc.relation.citationstartpage14592
dc.relation.citationendpage14602
dc.publisher.facultyFacultad de Ingenieríasspa
dc.affiliationLópez, J.E., Environmental Engineering Faculty, Universidad de Medellín, Medellín, 050026, Colombia
dc.affiliationBuiles, S., Departamento de Ingeniería de Procesos, Universidad EAFIT, Carrera 49 No. 7 sur-50, Medellín, 050022, Colombia
dc.affiliationHeredia Salgado, M.A., Department of Environment and Planning, Centre for Environmental and Marine Studies (CESAM), University of Aveiro, Aveiro, 3810-193, Portugal
dc.affiliationTarelho, L.A.C., Department of Environment and Planning, Centre for Environmental and Marine Studies (CESAM), University of Aveiro, Aveiro, 3810-193, Portugal
dc.affiliationArroyave, C., Environmental Engineering Faculty, Universidad de Medellín, Medellín, 050026, Colombia
dc.affiliationAristizábal, A., Departamento de Ingeniería de Procesos, Universidad EAFIT, Carrera 49 No. 7 sur-50, Medellín, 050022, Colombia
dc.affiliationChavez, E., Facultad de Ciencias de la Vida, Escuela Superior Politécnica del Litoral, ESPOL, Campus Gustavo Galindo Km. 30.5 Vía Perimetral, P.O. Box 09-01-5863, Guayaquil, Ecuador
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