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Excitation-dependent fluorescence from atomic/molecular layer deposited sodium-uracil thin films

dc.creatorPale V.spa
dc.creatorGiedraityte Z.spa
dc.creatorChen X.spa
dc.creatorLopez-Acevedo O.spa
dc.creatorTittonen I.spa
dc.creatorKarppinen M.spa
dc.date.accessioned2017-12-19T19:36:43Z
dc.date.available2017-12-19T19:36:43Z
dc.date.created2017
dc.identifier.issn20452322
dc.identifier.urihttp://hdl.handle.net/11407/4269
dc.description.abstractAtomic/molecular layer deposition (ALD/MLD) offers unique possibilities in the fabrication of inorganic-organic thin films with novel functionalities. Especially, incorporating nucleobases in the thin-film structures could open new avenues in the development of bio-electronic and photonic devices. Here we report an intense blue and widely excitation-dependent fluorescence in the visible region for ALD/MLD fabricated sodium-uracil thin films, where the crystalline network is formed from hydrogen-bonded uracil molecules linked via Na atoms. The excitation-dependent fluorescence is caused by the red-edge excitation shift (REES) effect taking place in the red-edge of the absorption spectrum, where the spectral relaxation occurs in continuous manner as demonstrated by the time-resolved measurements. © 2017 The Author(s).eng
dc.language.isoeng
dc.publisherNature Publishing Groupspa
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85026758688&doi=10.1038%2fs41598-017-07456-6&partnerID=40&md5=3cc11f20b262a5fa60a9cba265a7b6dfspa
dc.sourceScopusspa
dc.titleExcitation-dependent fluorescence from atomic/molecular layer deposited sodium-uracil thin filmsspa
dc.typeArticleeng
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.contributor.affiliationPale, V., Department of Electronics and Nanoengineering, Aalto University, Aalto, Finlandspa
dc.contributor.affiliationGiedraityte, Z., Department of Chemistry and Materials Science, Aalto University, Aalto, Finlandspa
dc.contributor.affiliationChen, X., COMP Centre of Excellence in Computational Nanoscience, Department of Applied Physics, Aalto University, Aalto, Finlandspa
dc.contributor.affiliationLopez-Acevedo, O., COMP Centre of Excellence in Computational Nanoscience, Department of Applied Physics, Aalto University, Aalto, Finland, Departamento de Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 # 30-65, Medellín, Colombiaspa
dc.contributor.affiliationTittonen, I., Department of Electronics and Nanoengineering, Aalto University, Aalto, Finlandspa
dc.contributor.affiliationKarppinen, M., Department of Chemistry and Materials Science, Aalto University, Aalto, Finlandspa
dc.identifier.doi10.1038/s41598-017-07456-6
dc.publisher.facultyFacultad de Ciencias Básicasspa
dc.abstractAtomic/molecular layer deposition (ALD/MLD) offers unique possibilities in the fabrication of inorganic-organic thin films with novel functionalities. Especially, incorporating nucleobases in the thin-film structures could open new avenues in the development of bio-electronic and photonic devices. Here we report an intense blue and widely excitation-dependent fluorescence in the visible region for ALD/MLD fabricated sodium-uracil thin films, where the crystalline network is formed from hydrogen-bonded uracil molecules linked via Na atoms. The excitation-dependent fluorescence is caused by the red-edge excitation shift (REES) effect taking place in the red-edge of the absorption spectrum, where the spectral relaxation occurs in continuous manner as demonstrated by the time-resolved measurements. © 2017 The Author(s).eng
dc.creator.affiliationDepartment of Electronics and Nanoengineering, Aalto University, Aalto, Finlandspa
dc.creator.affiliationDepartment of Chemistry and Materials Science, Aalto University, Aalto, Finlandspa
dc.creator.affiliationCOMP Centre of Excellence in Computational Nanoscience, Department of Applied Physics, Aalto University, Aalto, Finlandspa
dc.creator.affiliationDepartamento de Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 # 30-65, Medellín, Colombiaspa
dc.relation.ispartofesScientific Reportsspa
dc.relation.ispartofesScientific Reports Volume 7, Issue 1, 1 December 2017spa
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dc.type.driverinfo:eu-repo/semantics/article
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellínspa
dc.identifier.instnameinstname:Universidad de Medellínspa


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