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Evaluating the removal of the antibiotic cephalexin from aqueous solutions using an adsorbent obtained from palm oil fiber

dc.contributor.authorAcelas N
dc.contributor.authorLopera S.M
dc.contributor.authorPorras J
dc.contributor.authorTorres-Palma R.A.
dc.date.accessioned2022-09-14T14:33:44Z
dc.date.available2022-09-14T14:33:44Z
dc.date.created2021
dc.identifier.issn14203049
dc.identifier.urihttp://hdl.handle.net/11407/7452
dc.descriptionThis study aimed to understand the adsorption process of cephalexin (CPX) from aqueous solution by a biochar produced from the fiber residue of palm oil. Scanning electron microscopy, Fourier transform infrared spectroscopy, Boehm titration, and the point of zero charge were used to characterize the morphology and surface functional groups of the adsorbent. Batch tests were carried out to evaluate the effects of the solution pH, temperature, and antibiotic structure. The adsorption behavior followed the Langmuir model and pseudo-second-order model with a maximum CPX adsorption capacity of 57.47 mg g−1. Tests on the thermodynamic behavior suggested that chemisorption occurs with an activation energy of 91.6 kJ mol−1 through a spontaneous endothermic process. Electrostatic interactions and hydrogen bonding represent the most likely adsorption mechanisms, although π–π interactions also appear to contribute. Finally, the CPX removal efficiency of the adsorbent was evaluated for synthetic matrices of municipal wastewater and urine. Promising results were obtained, indicating that this adsorbent can potentially be applied to purifying wastewater that contains trace antibiotics. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.eng
dc.language.isoeng
dc.publisherMDPI AG
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85108110026&doi=10.3390%2fmolecules26113340&partnerID=40&md5=fbc319bb882408c119677314a9cff076
dc.sourceMolecules
dc.titleEvaluating the removal of the antibiotic cephalexin from aqueous solutions using an adsorbent obtained from palm oil fiber
dc.typeArticle
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.publisher.programCiencias Básicas
dc.type.spaArtículo
dc.identifier.doi10.3390/molecules26113340
dc.subject.keywordAdsorptioneng
dc.subject.keywordBiochareng
dc.subject.keywordCephalexineng
dc.subject.keywordIsothermeng
dc.subject.keywordKineticseng
dc.subject.keywordWastewatereng
dc.relation.citationvolume26
dc.relation.citationissue11
dc.publisher.facultyFacultad de Ciencias Básicas
dc.affiliationAcelas, N., Grupo de Materiales con Impacto, MAT and MPAC, Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, 050010, Colombia
dc.affiliationLopera, S.M., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, 050010, Colombia
dc.affiliationPorras, J., Grupo de Investigaciones Biomédicas Uniremington, Facultad de Ciencias de la Salud, Corporación Universitaria Remington (Uniremington), Calle 51 No. 51-27, Medellín, 050010, Colombia
dc.affiliationTorres-Palma, R.A., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, 050010, Colombia
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