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Experimental and theoretical insights on methylene blue removal from wastewater using an adsorbent obtained from the residues of the orange industry

dc.contributor.authorGiraldo S
dc.contributor.authorRobles I
dc.contributor.authorGodínez L.A
dc.contributor.authorAcelas N
dc.contributor.authorFlórez E.
dc.date.accessioned2022-09-14T14:33:44Z
dc.date.available2022-09-14T14:33:44Z
dc.date.created2021
dc.identifier.issn14203049
dc.identifier.urihttp://hdl.handle.net/11407/7456
dc.descriptionChemical and thermochemical transformations were performed on orange peel to obtain materials that were characterized and further tested to explore their potential as adsorbents for the removal of methylene blue (MB) from aqueous solutions. The results show the high potential of some of these materials for MB adsorption not only due to the surface area of the resulting substrate but also to the chemistry of the corresponding surface functional groups. Fitting of the kinetic as well as the equilibrium experimental data to different models suggests that a variety of interactions are involved in MB adsorption. The overall capacities for these substrates (larger than 192.31 mg g−1) were found to compare well with those reported for activated carbon and other adsorbents of agro-industrial origin. According to these results and complementary with theoretical study using Density Functional Theory (DFT) approximations, it was found that the most important adsorption mechanisms of MB correspond to: (i) electrostatic interactions, (ii) H-bonding, and (iii) π (MB)–π (biochar) interactions. In view of these findings, it can be concluded that adsorbent materials obtained from orange peel, constitute a good alternative for the removal of MB dye from aqueous solutions. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.eng
dc.language.isoeng
dc.publisherMDPI AG
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85111729643&doi=10.3390%2fmolecules26154555&partnerID=40&md5=76ec71145e0e9973274a6669187c38fd
dc.sourceMolecules
dc.titleExperimental and theoretical insights on methylene blue removal from wastewater using an adsorbent obtained from the residues of the orange industry
dc.typeArticle
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.publisher.programCiencias Básicas
dc.type.spaArtículo
dc.identifier.doi10.3390/molecules26154555
dc.subject.keywordAdsorptioneng
dc.subject.keywordAdsorption mechanismeng
dc.subject.keywordDFTeng
dc.subject.keywordDyeseng
dc.subject.keywordOrange peeleng
dc.relation.citationvolume26
dc.relation.citationissue15
dc.publisher.facultyFacultad de Ciencias Básicas
dc.affiliationGiraldo, S., Grupo de Investigación Materiales con Impacto (Mat&mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
dc.affiliationRobles, I., Centro de Investigación y Desarrollo Tecnológico en Electroquímica S. C., Parque Tecnológico Querétaro, Sanfandila, Pedro Escobedo, Querétaro, 76703, Mexico
dc.affiliationGodínez, L.A., Centro de Investigación y Desarrollo Tecnológico en Electroquímica S. C., Parque Tecnológico Querétaro, Sanfandila, Pedro Escobedo, Querétaro, 76703, Mexico
dc.affiliationAcelas, N., Grupo de Investigación Materiales con Impacto (Mat&mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
dc.affiliationFlórez, E., Grupo de Investigación Materiales con Impacto (Mat&mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia
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dc.identifier.instnameinstname:Universidad de Medellín


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