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dc.contributor.authorGrisales-Cifuentes C.M
dc.contributor.authorSerna Galvis E.A
dc.contributor.authorPorras J
dc.contributor.authorFlórez E
dc.contributor.authorTorres-Palma R.A
dc.contributor.authorAcelas N.
dc.date.accessioned2022-09-14T14:33:52Z
dc.date.available2022-09-14T14:33:52Z
dc.date.created2021
dc.identifier.issn9608524
dc.identifier.urihttp://hdl.handle.net/11407/7503
dc.descriptionAcetaminophen (ACE), cephalexin (CPX), and valsartan (VAL) are recognized water pollutants, which can be removed by adsorption. Herein, the removal of these pharmaceuticals using a biochar (BP), prepared from oil palm fiber, was tested. It was studied the structural effects of the pharmaceuticals and biochar on the adsorption process supported by experimental and computational results, plus characterizations of the material. The biochar has 76.05 m2 g−1 of surficial area, and carboxylic groups (1.343 mmol g−1) predominantly. The maximum adsorption uptakes were 7.3, 7.9, and 23.85 mg g−1 for ACE, CPX, and VAL, respectively; following pseudo-second-order kinetics. The best pollutants removal was obtained at acidic pH (3.0). Computational analyses indicated that oxygenated groups of BP (able to generate H-bond interactions) influenced the adsorption of pharmaceuticals. It can be remarked that BP is a low-cost adsorbent synthesized easily from wastes, with high feasibility to remove pharmaceutical structures from water. © 2021 Elsevier Ltdeng
dc.language.isoeng
dc.publisherElsevier Ltd
dc.relation.isversionofhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85100378728&doi=10.1016%2fj.biortech.2021.124753&partnerID=40&md5=f7cde10feeab84b9e3ea06acc49d17c8
dc.sourceBioresource Technology
dc.titleKinetics, isotherms, effect of structure, and computational analysis during the removal of three representative pharmaceuticals from water by adsorption using a biochar obtained from oil palm fiber
dc.typeArticle
dc.rights.accessrightsinfo:eu-repo/semantics/restrictedAccess
dc.publisher.programCiencias Básicas
dc.type.spaArtículo
dc.identifier.doi10.1016/j.biortech.2021.124753
dc.subject.keywordBiochareng
dc.subject.keywordPalm fiber wasteeng
dc.subject.keywordPharmaceuticals adsorptioneng
dc.subject.keywordStructural effectseng
dc.subject.keywordWater treatmenteng
dc.relation.citationvolume326
dc.publisher.facultyFacultad de Ciencias Básicas
dc.affiliationGrisales-Cifuentes, C.M., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia
dc.affiliationSerna Galvis, E.A., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia, Grupo de Investigaciones Biomédicas Uniremington, Facultad de Ciencias de la Salud, Corporación Universitaria Remington (Uniremington), Calle 51 No. 51-27, Medellín, Colombia
dc.affiliationPorras, J., Grupo de Investigaciones Biomédicas Uniremington, Facultad de Ciencias de la Salud, Corporación Universitaria Remington (Uniremington), Calle 51 No. 51-27, Medellín, Colombia
dc.affiliationFlórez, E., Grupo de Materiales con Impacto, Mat&mpac, Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, Colombia
dc.affiliationTorres-Palma, R.A., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia
dc.affiliationAcelas, N., Grupo de Materiales con Impacto, Mat&mpac, Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, Colombia
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dc.type.coarhttp://purl.org/coar/resource_type/c_6501
dc.type.versioninfo:eu-repo/semantics/publishedVersion
dc.type.driverinfo:eu-repo/semantics/article
dc.identifier.reponamereponame:Repositorio Institucional Universidad de Medellín
dc.identifier.repourlrepourl:https://repository.udem.edu.co/
dc.identifier.instnameinstname:Universidad de Medellín


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