dc.contributor.author | Hernández-Navarro C | |
dc.contributor.author | Pérez S | |
dc.contributor.author | Flórez E | |
dc.contributor.author | Acelas N | |
dc.contributor.author | Muñoz-Saldaña J. | |
dc.date.accessioned | 2023-10-24T19:24:30Z | |
dc.date.available | 2023-10-24T19:24:30Z | |
dc.date.created | 2023 | |
dc.identifier.issn | 3014797 | |
dc.identifier.uri | http://hdl.handle.net/11407/7959 | |
dc.description.abstract | Currently, the large volumes of Sargassum biomass (Sgs) arriving on Caribbean coasts are a problem that must be solved quickly. One alternative is to obtain value-added products from Sgs. In this work, Sgs is demonstrated to be a high-performance Ca - bioadsorbent for phosphate removal by a heat pretreatment at 800 °C that produces biochar. According to XRD analysis, calcined Sgs (CSgs) have a composition of 43.68%, 40.51%, and 8.69% of Ca(OH)2, CaCO3, and CaO, making CSgs a promising material for phosphate removal and recovery. Results demonstrated that CSgs have a high capacity to adsorb P over a wide range of concentrations (25–1000 mg P/L). After P removal, at low P concentration, the adsorbent material is rich in apatite (Ca5(PO4)3OH), and at high P concentration, brushite (CaHPO4•2H2O) was the main P compound. The CSg reached a Qmax of 224.58 mg P/g, which is higher than other high-performance adsorbents reported in the literature. The phosphate adsorption mechanism was dominated by chemisorption, followed by precipitation according to the pseudo-second-order kinetic model. The solubility of P (74.5 wt%) in formic acid solution and the water-soluble P (24.8 wt%) for CSgs after P adsorption indicated that the final product presents the potential to be used as fertilizer for acid soils. This biomass's processability and high phosphate adsorption performance for P removal make CSgs a potential material for wastewater treatment, and subsequent use of these residues as fertilizer offers a circular economy solution to this problem. © 2023 Elsevier Ltd | eng |
dc.language.iso | eng | |
dc.publisher | Academic Press | |
dc.relation.isversionof | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160730778&doi=10.1016%2fj.jenvman.2023.118312&partnerID=40&md5=c7115f7dc870a10653ed31d47983715a | |
dc.source | J. Environ. Manage. | |
dc.source | Journal of Environmental Management | eng |
dc.subject | Adsorption | eng |
dc.subject | Calcium phosphate | eng |
dc.subject | Circular economy | eng |
dc.subject | Sargassum macroalgae | eng |
dc.subject | Wastewater | eng |
dc.title | Sargassummacroalgae from Quintana Roo as raw material for the preparation of high-performance phosphate adsorbent from aqueous solutions | eng |
dc.type | Article | |
dc.rights.accessrights | info:eu-repo/semantics/restrictedAccess | |
dc.publisher.program | Ciencias Básicas | spa |
dc.type.spa | Artículo | |
dc.identifier.doi | 10.1016/j.jenvman.2023.118312 | |
dc.relation.citationvolume | 342 | |
dc.publisher.faculty | Facultad de Ciencias Básicas | spa |
dc.affiliation | Hernández-Navarro, C., Laboratorio Nacional de Proyección Térmica (CENAPROT), Centro de Investigación y de Estudios Avanzados Del IPN, Libramiento Norponiente 2000 Fracc. Real de Juriquilla, Querétaro, 76230, Mexico, Tecnológico Nacional de México CRODE-Celaya, Centro de Vinculación para la Innovación y Desarrollo Empresarial (CEVIDE), Departamento de Diseño y Desarrollo de Equipo, Col. Residencial Tecnológico, Manuel Orozco I. Berra 92, Guanajuato, Celaya, 38010, Mexico | |
dc.affiliation | Pérez, S., Laboratorio Nacional de Proyección Térmica (CENAPROT), Centro de Investigación y de Estudios Avanzados Del IPN, Libramiento Norponiente 2000 Fracc. Real de Juriquilla, Querétaro, 76230, Mexico | |
dc.affiliation | Flórez, E., Grupo de Investigación Materiales con Impacto (Mat&mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia | |
dc.affiliation | Acelas, N., Grupo de Investigación Materiales con Impacto (Mat&mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia | |
dc.affiliation | Muñoz-Saldaña, J., Laboratorio Nacional de Proyección Térmica (CENAPROT), Centro de Investigación y de Estudios Avanzados Del IPN, Libramiento Norponiente 2000 Fracc. Real de Juriquilla, Querétaro, 76230, Mexico | |
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dc.type.version | info:eu-repo/semantics/publishedVersion | |
dc.identifier.reponame | reponame:Repositorio Institucional Universidad de Medellín | |
dc.identifier.repourl | repourl:https://repository.udem.edu.co/ | |
dc.identifier.instname | instname:Universidad de Medellín | |