| dc.contributor.author | Grisales-Cifuentes C.M | |
| dc.contributor.author | Serna-Galvis E.A | |
| dc.contributor.author | Acelas N | |
| dc.contributor.author | Porras J | |
| dc.contributor.author | Flórez E | |
| dc.contributor.author | Torres-Palma R.A. | |
| dc.date.accessioned | 2023-10-24T19:24:49Z | |
| dc.date.available | 2023-10-24T19:24:49Z | |
| dc.date.created | 2022 | |
| dc.identifier.issn | 3014797 | |
| dc.identifier.uri | http://hdl.handle.net/11407/8002 | |
| dc.description.abstract | Biochar (BP) obtained from palm fiber wastes was combined with H2O2, peroxymonosulfate (PMS), or persulfate (PDS) to treat valsartan, acetaminophen, and cephalexin in water. BP activated PMS and PDS but no H2O2. Computational calculations indicated that interactions of PMS and PDS with BP are more favored than those with HP. The highest synergistic effect was obtained for the removal of valsartan by BP + PMS. This carbocatalytic process was optimized, evaluating the effects of pH, BP dose, and peroxymonosulfate concentration, and minimizing the oxidant quantity to decrease costs and environmental impacts of the process. SO4•−, HO•, 1O2, and O2•- were the agents involved in the degradation of the pharmaceuticals. The reusability of BP was tested, showing that the carbocatalytic process removed ∼80% of target pollutants after 120 min of treatment even at the fourth reuse cycle. Also, the process decreased the phytotoxicity of the treated sample. Simulated hospital wastewater was treated and its components induced competing effects, but the system achieved the target pharmaceuticals removal in this matrix. Additionally, the analysis of environmental impact using a life cycle assessment unraveled that the carbocatalytic process had a carbon footprint of 2.87 Kg CO2-Eq, with the biochar preparation (which involves the use of ZnCl2 and electric energy consumption) as the main hotspot in the process. © 2022 Elsevier Ltd | eng |
| dc.language.iso | eng | |
| dc.publisher | Academic Press | |
| dc.relation.isversionof | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85137396255&doi=10.1016%2fj.jenvman.2022.116148&partnerID=40&md5=c7e506c8c5b4f6ea0f20e1e3491ae5a6 | |
| dc.source | J. Environ. Manage. | |
| dc.source | Journal of Environmental Management | eng |
| dc.subject | Biochar | eng |
| dc.subject | Carbocatalysis | eng |
| dc.subject | Environmental analysis | eng |
| dc.subject | Oxidants activation | eng |
| dc.subject | Pharmaceuticals removal | eng |
| dc.subject | Water treatment | eng |
| dc.title | Biochar from palm fiber wastes as an activator of different oxidants for the elimination of pharmaceuticals from diverse classes in aqueous samples | eng |
| dc.type | Article | |
| dc.rights.accessrights | info:eu-repo/semantics/restrictedAccess | |
| dc.publisher.program | Ciencias Básicas | spa |
| dc.type.spa | Artículo | |
| dc.identifier.doi | 10.1016/j.jenvman.2022.116148 | |
| dc.relation.citationvolume | 323 | |
| dc.publisher.faculty | Facultad de Ciencias Básicas | spa |
| dc.affiliation | Grisales-Cifuentes, C.M., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia | |
| dc.affiliation | Serna-Galvis, E.A., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia, Grupo de Catalizadores y Adsorbentes (CATALAD), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 # 52-21, Medellín, Colombia | |
| dc.affiliation | Acelas, N., Grupo de Materiales con Impacto, Mat&mpac. Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, Colombia | |
| dc.affiliation | Porras, J., Grupo de Investigaciones Biomédicas Uniremington, Facultad de Ciencias de La Salud, Corporación Universitaria Remington (Uniremington), Calle 51 No. 51-27, Medellín, Colombia | |
| dc.affiliation | Flórez, E., Grupo de Materiales con Impacto, Mat&mpac. Facultad de Ciencias Básicas, Universidad de Medellín, Medellín, Colombia | |
| dc.affiliation | Torres-Palma, R.A., Grupo de Investigación en Remediación Ambiental y Biocatálisis (GIRAB), Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín, Colombia | |
| dc.relation.references | Ahangarnokolaei, M.A., Attarian, P., Ayati, B., Ganjidoust, H., Rizzo, L., Life cycle assessment of sequential and simultaneous combination of electrocoagulation and ozonation for textile wastewater treatment (2021) J. Environ. Chem. Eng., 106251 | |
| dc.relation.references | Bangari, R.S., Sinha, N., Adsorption of tetracycline, ofloxacin and cephalexin antibiotics on boron nitride nanosheets from aqueous solution (2019) J. Mol. Liq., 293 | |
| dc.relation.references | Belalcázar-Saldarriaga, A., Prato-Garcia, D., Vasquez-Medrano, R., Photo-Fenton processes in raceway reactors: technical, economic, and environmental implications during treatment of colored wastewaters (2018) J. Clean. Prod., 182, pp. 818-829 | |
| dc.relation.references | Bielski, B.H.J., Cabelli, D.E., Arudi, R.L., Ross, A.B., Reactivity of HO2/O−2 radicals in aqueous solution (1985) J. Phys. Chem. Ref. Data, 14, pp. 1041-1100 | |
| dc.relation.references | Bruycker, K.D., Recyclable cross-linked hydroxythioether particles with tunable structures via robust and efficient thiol-epoxy dispersion polymerizations (2017) RSC Adv., 7, pp. 51763-51772 | |
| dc.relation.references | Cai, S., Zhang, Q., Wang, Z., Hua, S., Ding, D., Cai, T., Zhang, R., Pyrrolic N-rich biochar without exogenous nitrogen doping as a functional material for bisphenol A removal: performance and mechanism (2021) Appl. Catal. B Environ., 291 | |
| dc.relation.references | Cai, S., Zuo, X., Zhao, H., Yang, S., Chen, R., Chen, L., Zhang, R., Cai, T., Evaluation of N-doped carbon for the peroxymonosulfate activation and removal of organic contaminants from livestock wastewater and groundwater (2022) J. Mater. Chem., 10, pp. 9171-9183 | |
| dc.relation.references | Carvalho Neves, L., Beber de Souza, J., de Souza Vidal, C.M., Herbert, L.T., de Souza, K.V., Geronazzo Martins, K., Young, B.J., Phytotoxicity indexes and removal of color, COD, phenols and ISA from pulp and paper mill wastewater post-treated by UV/H2O2 and photo-Fenton (2020) Ecotoxicol. Environ. Saf., 202 | |
| dc.relation.references | Chen, L., Yang, S., Zuo, X., Huang, Y., Cai, T., Ding, D., Biochar modification significantly promotes the activity of Co3O4 towards heterogeneous activation of peroxymonosulfate (2018) Chem. Eng. J., 354, pp. 856-865 | |
| dc.relation.references | Chen, X., Oh, W.D., Lim, T.T., Graphene-and CNTs-based carbocatalysts in persulfates activation: material design and catalytic mechanisms (2018) Chem. Eng. J., 354, pp. 941-976 | |
| dc.relation.references | Dai, J., Yan, J., Ding, D., Cai, T., Dissolved black carbon induced elimination of bisphenol a by peroxymonosulfate activation through HClO mediated oxidation process (2022) Chem. Eng. J., 446 | |
| dc.relation.references | Devi, P., Das, U., Dalai, A.K., In-situ chemical oxidation: principle and applications of peroxide and persulfate treatments in wastewater systems (2016) Sci. Total Environ. | |
| dc.relation.references | Dewil, R., Mantzavinos, D., Poulios, I., Rodrigo, M.A., New perspectives for advanced oxidation processes (2017) J. Environ. Manag., 195, pp. 93-99 | |
| dc.relation.references | Díez-Mato, E., Cortezón-Tamarit, F.C., Bogialli, S., García-Fresnadillo, D., Marazuela, M.D., Phototransformation of model micropollutants in water samples by photocatalytic singlet oxygen production in heterogeneous medium (2014) Appl. Catal. B Environ., 160-161, pp. 445-455 | |
| dc.relation.references | Farré, M.J., García-Montaño, J., Ruiz, N., Muñoz, I., Domènech, X., Peral, J., Life cycle assessment of the removal of Diuron and Linuron herbicides from water using three environmentally friendly technologies (2007) Environ. Technol., 28, pp. 819-830 | |
| dc.relation.references | Foteinis, S., Monteagudo, J.M., Durán, A., Chatzisymeon, E., Environmental sustainability of the solar photo-Fenton process for wastewater treatment and pharmaceuticals mineralization at semi-industrial scale (2018) Sci. Total Environ., 612, pp. 605-612 | |
| dc.relation.references | Ghanbari, F., Giannakis, S., Samoili, S., Chapter 10 persulfate application for landfill leachate treatment: current status and challenges (2022) Persulfate-Based Oxidation Processes in Environmental Remediation, pp. 252-288. , The Royal Society of Chemistry | |
| dc.relation.references | Grisales-Cifuentes, C.M., Serna Galvis, E.A., Porras, J., Flórez, E., Torres-Palma, R.A., Acelas, N., Kinetics, isotherms, effect of structure, and computational analysis during the removal of three representative pharmaceuticals from water by adsorption using a biochar obtained from oil palm fiber (2021) Bioresour. Technol., 326 | |
| dc.relation.references | Grisales, C.M., Salazar, L.M., Garcia, D.P., Treatment of synthetic dye baths by Fenton processes: evaluation of their environmental footprint through life cycle assessment (2019) Environ. Sci. Pollut. Res., 26, pp. 4300-4311 | |
| dc.relation.references | Guinée, J., Gorree, M., Heijungs, R., Huppes, G., Kleijn, R., Haes, H., Voet, E., Life Cycle Assessment an Operational Guide to the ISO Standards (2001) | |
| dc.relation.references | Hayyan, M., Hashim, M.A., Alnashef, I.M., Superoxide ion: generation and chemical implications (2016) Chem. Rev., 116, pp. 3029-3085 | |
| dc.relation.references | Huang, S., Wang, T., Chen, K., Mei, M., Liu, J., Li, J., Engineered biochar derived from food waste digestate for activation of peroxymonosulfate to remove organic pollutants (2020) Waste Manag., 107, pp. 211-218 | |
| dc.relation.references | Jaafarzadeh, N., Ghanbari, F., Zahedi, A., Coupling electrooxidation and Oxone for degradation of 2,4-Dichlorophenoxyacetic acid (2,4-D) from aqueous solutions (2018) J. Water Proc. Eng., 22, pp. 203-209 | |
| dc.relation.references | Kiejza, D., Kotowska, U., Poli, W., Karpi, J., Peracids - new oxidants in advanced oxidation processes: the use of peracetic acid, peroxymonosulfate, and persulfate salts in the removal of organic micropollutants of emerging concern − A review (2021) Sci. Total Environ., 790 | |
| dc.relation.references | Lee, J., von Gunten, U., Kim, J., Persulfate-based advanced oxidation: critical assessment of opportunities and roadblocks (2020) Environ. Sci. Technol., 54, pp. 3064-3081. , () https://doi.org/ca | |
| dc.relation.references | Li, F., Duan, F., Ji, W., Gui, X., Biochar-activated persulfate for organic contaminants removal: efficiency, mechanisms and influencing factors (2020) Ecotoxicol. Environ. Saf., 198 | |
| dc.relation.references | Libralato, G., Costa Devoti, A., Zanella, M., Sabbioni, E., Mičetić, I., Manodori, L., Pigozzo, A., Volpi Ghirardini, A., Phytotoxicity of ionic, micro- and nano-sized iron in three plant species (2016) Ecotoxicol. Environ. Saf., 123 | |
| dc.relation.references | Liu, T., Zhang, D., Yin, K., Yang, C., Luo, S., Crittenden, J.C., Degradation of thiacloprid via unactivated peroxymonosulfate: the overlooked singlet oxygen oxidation (2020) Chem. Eng. J., 388 | |
| dc.relation.references | Liu, T., Zhang, D., Yin, K., Yang, C., Luo, S., Crittenden, J.C., Degradation of thiacloprid via unactivated peroxymonosulfate: the overlooked singlet oxygen oxidation (2020) Chem. Eng. J., 388 | |
| dc.relation.references | Liu, Y., Lin, Q., Guo, Y., Zhao, J., Luo, X., Zhang, H., Li, G., Liang, H., The nitrogen-doped multi-walled carbon nanotubes modified membrane activated peroxymonosulfate for enhanced degradation of organics and membrane fouling mitigation in natural waters treatment (2022) Water Res., 209 | |
| dc.relation.references | Luo, J., Gao, Y., Song, T., Chen, Y., Activation of peroxymonosulfate by biochar and biochar-based materials for degrading refractory organics in water: a review (2021) Water Sci. Technol., 83, pp. 2327-2344 | |
| dc.relation.references | Luo, K., Yang, Q., Pang, Y., Wang, D., Li, X., Lei, M., Huang, Q., Unveiling the mechanism of biochar-activated hydrogen peroxide on the degradation of ciprofloxacin (2019) Chem. Eng. J., 374 | |
| dc.relation.references | Lykoudi, A., Frontistis, Z., Vakros, J., Manariotis, I.D., Mantzavinos, D., Degradation of sulfamethoxazole with persulfate using spent coffee grounds biochar as activator (2020) J. Environ. Manag., 271 | |
| dc.relation.references | Magdy, M., Gar, M., El-etriby, H.K., Comparative life cycle assessment of fi ve chemical methods for removal of phenol and its transformation products (2021) J. Clean. Prod., 291 | |
| dc.relation.references | Mañas, P., De las Heras, J., Phytotoxicity test applied to sewage sludge using Lactuca sativa L. and Lepidium sativum L. seeds (2018) Int. J. Environ. Sci. Technol., 15, pp. 273-280 | |
| dc.relation.references | Martínez-Pachón, D., Serna-Galvis, E.A., Ibañez, M., Hernández, F., Ávila-Torres, Y., Torres-Palma, R.A., Moncayo-Lasso, A., Treatment of two sartan antihypertensives in water by photo-electro-Fenton using BDD anodes: degradation kinetics, theoretical analyses, primary transformations and matrix effects (2021) Chemosphere, 270 | |
| dc.relation.references | Mian, M.M., Liu, G., Activation of peroxymonosulfate by chemically modified sludge biochar for the removal of organic pollutants: understanding the role of active sites and mechanism (2020) Chem. Eng. J., 392 | |
| dc.relation.references | Muñoz, I., Feral, J., Ayllón, J.A., Malato, S., Martin, M.J., Perrot, J.Y., Vincent, M., Domènech, X., Life-cycle assessment of a coupled advanced oxidation-biological process for wastewater treatment: comparison with granular activated carbon adsorption (2007) Environ. Eng. Sci., 24, pp. 638-651 | |
| dc.relation.references | Myers, R.H., Montgomery, D.C., Anderson, C., Response surface methodology: process and product optimization using designed experiments (1997) J. Stat. Plann. Inference, 59, pp. 185-186 | |
| dc.relation.references | Ouyang, D., Chen, Y., Yan, J., Qian, L., Han, L., Chen, M., Activation mechanism of peroxymonosulfate by biochar for catalytic degradation of 1,4-dioxane: important role of biochar defect structures (2019) Chem. Eng. J., 370, pp. 614-624 | |
| dc.relation.references | Paredes-Laverde, M., Silva-Agredo, J., Torres-Palma, R.A., Removal of norfloxacin in deionized, municipal water and urine using rice (Oryza sativa) and coffee (Coffea arabica) husk wastes as natural adsorbents (2018) J. Environ. Manag., 213, pp. 98-108 | |
| dc.relation.references | Patel, M., Kumar, R., Kishor, K., Mlsna, T., Pittman, C.U., Mohan, D., Pharmaceuticals of emerging concern in aquatic systems: chemistry, occurrence, effects, and removal methods (2019) Chem. Rev., 119, pp. 3510-3673 | |
| dc.relation.references | Rivera-Utrilla, J., Sánchez-Polo, M., Ferro-García, M.Á., Prados-Joya, G., Ocampo-Pérez, R., Pharmaceuticals as emerging contaminants and their removal from water. A review (2013) Chemosphere, 93, pp. 1268-1287 | |
| dc.relation.references | Rodríguez-Chueca, J., Giannakis, S., Marjanovic, M., Kohantorabi, M., Gholami, M.R., Grandjean, D., de Alencastro, L.F., Pulgarín, C., Solar-assisted bacterial disinfection and removal of contaminants of emerging concern by Fe2+-activated HSO5- vs. S2O82- in drinking water (2019) Appl. Catal. B Environ., 248, pp. 62-72 | |
| dc.relation.references | Sabzehmeidani, M.M., Mahnaee, S., Ghaedi, M., Heidari, H., Roy, V.A.L., Carbon based materials: a review of adsorbents for inorganic and organic compounds (2021) Mater. Adv., 2, pp. 598-627 | |
| dc.relation.references | Salazar, L.M., Grisales, C.M., Garcia, D.P., How does intensification influence the operational and environmental performance of photo-Fenton processes at acidic and circumneutral pH (2019) Environ. Sci. Pollut. Res., 26, pp. 4367-4380 | |
| dc.relation.references | Sbardella, L., Velo, I., Comas, J., Integrated assessment of sulfate-based AOPs for pharmaceutical active compound removal from wastewater (2020) J. Clean. Prod., 260 | |
| dc.relation.references | Seburg, R.A., Ballard, J.M., Hwang, T., Sullivan, C.M., (2006) Photosensitized Degradation of Losartan Potassium in an Extemporaneous Suspension Formulation, 42, pp. 411-422 | |
| dc.relation.references | Serna-Galvis, Efraim, A., Isaza-Pineda, L., Moncayo-Lasso, A., Hernández, F., Ibáñez, M., Torres-Palma, R.A., Comparative degradation of two highly consumed antihypertensives in water by sonochemical process. Determination of the reaction zone, primary degradation products and theoretical calculations on the oxidative process (2019) Ultrason. Sonochem., 58 | |
| dc.relation.references | Serna-Galvis, Efraím, A., Silva-Agredo, J., Botero-Coy, A.M., Moncayo-Lasso, A., Hernández, F., Torres-Palma, R.A., Effective elimination of fifteen relevant pharmaceuticals in hospital wastewater from Colombia by combination of a biological system with a sonochemical process (2019) Sci. Total Environ., 670, pp. 623-632 | |
| dc.relation.references | Shan, R., Han, J., Gu, J., Yuan, H., Luo, B., Chen, Y., A review of recent developments in catalytic applications of biochar-based materials (2020) Resour. Conserv. Recycl. | |
| dc.relation.references | Solís, R.R., Mena, I.F., Nadagouda, M.N., Dionysiou, D.D., Adsorptive interaction of peroxymonosulfate with graphene and catalytic assessment via non-radical pathway for the removal of aqueous pharmaceuticals (2020) J. Hazard Mater., 384 | |
| dc.relation.references | Sun, C., Chen, T., Huang, Q., Zhan, M., Li, X., Yan, J., Activation of persulfate by CO2-activated biochar for improved phenolic pollutant degradation: performance and mechanism (2020) Chem. Eng. J., 380 | |
| dc.relation.references | Wacławek, S., Lutze, H.V., Grübel, K., Padil, V.V.T., Černík, M., Dionysiou, D.D., Chemistry of persulfates in water and wastewater treatment: a review (2017) Chem. Eng. J., 330, pp. 44-62 | |
| dc.relation.references | Wang, J., Shen, M., Wang, H., Du, Y., Zhou, X., Liao, Z., Wang, H., Chen, Z., Red mud modified sludge biochar for the activation of peroxymonosulfate: singlet oxygen dominated mechanism and toxicity prediction (2020) Sci. Total Environ., 740 | |
| dc.relation.references | Wang, J., Wang, S., Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants (2018) Chem. Eng. J. | |
| dc.relation.references | Wang, Y., Dong, H., Li, L., Tian, R., Chen, J., Ning, Q., Wang, B., Zeng, G., Influence of feedstocks and modification methods on biochar's capacity to activate hydrogen peroxide for tetracycline removal (2019) Bioresour. Technol., 291 | |
| dc.relation.references | Wang, Z., Du, C., Ding, D., Chen, R., Yang, S., Cai, T., Recent advances in metal-free catalysts for the remediation of antibiotics, antibiotic resistant bacteria (ARB), and antibiotic resistant genes (ARGs) (2022) J. Mater. Chem., 10, pp. 15235-15266 | |
| dc.relation.references | Wei, J., Liu, Y., Zhu, Y., Li, J., Enhanced catalytic degradation of tetracycline antibiotic by persulfate activated with modified sludge bio-hydrochar (2020) Chemosphere, 247 | |
| dc.relation.references | Yan, J., Zuo, X., Yang, S., Chen, R., Cai, T., Ding, D., Evaluation of potassium ferrate activated biochar for the simultaneous adsorption of copper and sulfadiazine: competitive versus synergistic (2022) J. Hazard Mater., 424 | |
| dc.relation.references | Yun, E.-T., Yoo, H.-Y., Bae, H., Kim, H.-I., Lee, J., Exploring the role of persulfate in the activation process: radical precursor versus electron acceptor (2017) Environ. Sci. Technol., 51, pp. 10090-10099 | |
| dc.relation.references | Zhang, R., Li, Y., Wang, Z., Tong, Y., Sun, P., Biochar-activated peroxydisulfate as an effective process to eliminate pharmaceutical and metabolite in hydrolyzed urine (2020) Water Res., 177 | |
| dc.relation.references | Zhao, C., Shao, B., Yan, M., Liu, Z., Liang, Q., He, Q., Wu, T., Tang, L., Activation of peroxymonosulfate by biochar-based catalysts and applications in the degradation of organic contaminants: a review (2021) Chem. Eng. J., 416 | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | |
| dc.identifier.reponame | reponame:Repositorio Institucional Universidad de Medellín | |
| dc.identifier.repourl | repourl:https://repository.udem.edu.co/ | |
| dc.identifier.instname | instname:Universidad de Medellín | |
