dc.contributor.author | Pérez S | |
dc.contributor.author | Giraldo S | |
dc.contributor.author | Forgionny A | |
dc.contributor.author | Flórez E | |
dc.contributor.author | Acelas N. | |
dc.date.accessioned | 2023-10-24T19:24:59Z | |
dc.date.available | 2023-10-24T19:24:59Z | |
dc.date.created | 2022 | |
dc.identifier.issn | 21906815 | |
dc.identifier.uri | http://hdl.handle.net/11407/8027 | |
dc.description.abstract | Large quantities of orange peel wastes are generated and require adequate management and disposal into the environment. Agricultural waste valorization is a strong research topic, due to the increasing need for achieving a sustainable environment. Especially, the development of adsorbent materials applied to wastewater treatment for efficient phosphorus recovery and reuse systems is a challenge of current interest in research. In this work, a novel low-cost biocomposite was obtained by calcination of orange peel (OP) and eggshell (ES), which is highly effective for P recovery from synthetic aqueous solutions and domestic wastewater. After calcination at 700 °C, the material with a ratio by weight of OP/ES = 1 showed a high adsorption capacity (Qmax = 315.25 mg P/g) compared to other materials previously reported. The XRD and FTIR characterization results of the materials after the P removal showed that brushite (Ca(HPO4)•2H2O) is the main calcium phase obtained at pH 6, while apatite (Ca5(PO4)3OH) is favored at a pH higher than 8. Moreover, the ESOP adsorbents showed a high P adsorption from wastewater, with 98.6% of P recovery as apatite. Additionally, Ca5(PO4)3OH and Ca(HPO4)•2H2O phases exhibited a high solubility of P in 2% formic acid releasing up to 97.50 and 194.22 mg P/g. The results of this work indicate that calcined ESOP is a promising material for P recovery from aqueous solution, forming calcium phosphates with great potential to be used as alternative phosphate fertilizer, contributing to implementing the 3R slogan “Reduce, Reuse, Recycle” based on a circular economy. © 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. | eng |
dc.language.iso | eng | |
dc.publisher | Springer Science and Business Media Deutschland GmbH | |
dc.relation.isversionof | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85132206624&doi=10.1007%2fs13399-022-02948-6&partnerID=40&md5=637e39576b77def6cf0364fea9e1ac20 | |
dc.source | Biomass Convers. Biorefinery | |
dc.source | Biomass Conversion and Biorefinery | eng |
dc.subject | Adsorption | eng |
dc.subject | Eggshell | eng |
dc.subject | Fertilizer | eng |
dc.subject | Orange peel | eng |
dc.subject | Phosphorus | eng |
dc.title | Eco-friendly reuse of agricultural wastes to produce biocomposites with high potential in water treatment and fertilizers | eng |
dc.type | Article | |
dc.rights.accessrights | info:eu-repo/semantics/restrictedAccess | |
dc.publisher.program | Ciencias Básicas | spa |
dc.type.spa | Artículo | |
dc.identifier.doi | 10.1007/s13399-022-02948-6 | |
dc.publisher.faculty | Facultad de Ciencias Básicas | spa |
dc.affiliation | Pérez, S., Grupo de Investigación Materiales Con Impacto (Mat&Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia | |
dc.affiliation | Giraldo, S., Grupo de Investigación Materiales Con Impacto (Mat&Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia | |
dc.affiliation | Forgionny, A., Grupo de Investigación Materiales Con Impacto (Mat&Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia | |
dc.affiliation | Flórez, E., Grupo de Investigación Materiales Con Impacto (Mat&Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia | |
dc.affiliation | Acelas, N., Grupo de Investigación Materiales Con Impacto (Mat&Mpac), Facultad de Ciencias Básicas, Universidad de Medellín, Carrera 87 No. 30-65, Medellín, 050026, Colombia | |
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dc.type.version | info:eu-repo/semantics/publishedVersion | |
dc.identifier.reponame | reponame:Repositorio Institucional Universidad de Medellín | |
dc.identifier.repourl | repourl:https://repository.udem.edu.co/ | |
dc.identifier.instname | instname:Universidad de Medellín | |